Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubes.

The main goal of this work was an improvement in the mechanical and electrical properties of acrylic resin-based nanocomposites filled with chemically modified carbon nanotubes. For this purpose, the surface functionalization of multi-walled carbon nanotubes (MWCNTs) was carried out by means of aryl groups grafting via the diazotization reaction with selected aniline derivatives, and then nanocomposites based on ELIUM® resin were fabricated. FT-IR analysis confirmed the effectiveness of the carried-out chemical surface modification of MWCNTs as new bands on FT-IR spectra appeared in the measurements. TEM observations showed that carbon nanotube fragmentation did not occur during the modifications. According to the results from Raman spectroscopy, the least defective carbon nanotube structure was obtained for aniline modification. Transmission light microscopy analysis showed that the neat MWCNTs agglomerate strongly, while the proposed modifications improved their dispersion significantly. Viscosity tests confirmed, that as the nanofiller concentration increases, the viscosity of the mixture increases. The mixture with the highest dispersion of nanoparticles exhibited the most viscous behaviour. Finally, an enhancement in impact resistance and electrical conductivity was obtained for nanocomposites containing modified MWCNTs.

Effect of High-Pressure Torsion on Phase Formation and Mechanical Properties of a High-Entropy TiZrHfMoCrCo Alloy.

This investigation delved into the alterations in the mechanical properties of a TiZrHfMoCrCo high-entropy alloy due to phase transformations induced by high-pressure torsion (HPT). The alloy's genesis involved levitation melting within an argon atmosphere, presenting two distinct states for analysis: the initial, post-manufacturing state and the state subsequent to HPT treatment. The original alloy featured a composition comprising a singular A2 phase with a bcc lattice and two Laves phases, C15 and C14. The HPT process triggered significant phase modifications: a retention of one C15 Laves phase and decomposition of the bcc phase into two distinct phases exhibiting different bcc lattice parameters. The HPT-induced effect prominently manifests as strong grain refinement. However, scanning electron microscopy (SEM) observations unveiled persistent inhomogeneities at a micron scale both before and after HPT treatment. Thus, grain refinement occurs separately within each of the bcc and Laves phases, visible in the light, dark, and gray areas in SEM images, while mixing does not occur on the scale of several microns. The examination of Ti, Cr, Co, Zr, Mo, and Hf via X-ray absorption spectroscopy (EXAFS) at specific K-edges and L3-edge revealed that the HPT treatment conserves the local atomic environment of metal atoms, albeit with a slight elevation in static disorder. Assessments through microhardness and three-point bending tests demonstrated the material's inherent hardness and brittleness. The microhardness, standing at a substantial value of 600 HV, displayed negligible augmentation post-HPT. However, the microhardness of individual phases exhibited a notable alteration, nearly doubling in magnitude.

Influence of Surface Preparation on the Microstructure and Mechanical Properties of Cold-Sprayed Nickel Coatings on Al 7075 Alloy.

This work presents the effect of surface roughness (Al 7075) on the microstructure and mechanical properties of cold-sprayed nickel coatings. Coating analysis included substrate surfaces and coating geometry, microstructure characterization, microhardness, nanohardness, elastic modulus, and adhesion. The results show that the surface preparation had a significant effect on coating adhesion and microstructure. The coating deposited at the highest gas temperature revealed a dense microstructure, showing very good adhesion of the impacting powder particles to the substrate and good bonding between deposited layers. The Ni grains with different shapes (elongated, equiaxed) and sizes of a few dozen to several hundred nanometres were present in the splats. An increase in temperature caused significant growth in coating thickness as a result of the powder grains' higher velocity. Moreover, higher gas temperature resulted in the enhancement of micro- and nanohardness, elastic modulus, and adhesion. The adhesive bond strength of Ni coatings in the tested temperature ranges from 500 °C to 800 °C increased with the increase in the surface roughness of the substrate. For the Al 7075 coarse grit-blasted (CG) substrate with the highest roughness, the adhesion reached the highest value of 44.6 MPa when the working gas was at a temperature of 800 °C. There were no distinct dependencies of surface roughness and thickness on the mechanical properties of the cold-sprayed nickel coating.

Exploring CVD Method for Synthesizing Carbon-Carbon Composites as Materials to Contact with Nerve Tissue.

The main purpose of these studies was to obtain carbon-carbon composites with a core built of carbon fibers and a matrix in the form of pyrolytic carbon (PyC), obtained by using the chemical vapor deposition (CVD) method with direct electrical heating of a bundle of carbon fibers as a potential electrode material for nerve tissue stimulation. The methods used for the synthesis of PyC proposed in this paper allow us, with the appropriate selection of parameters, to obtain reproducible composites in the form of rods with diameters of about 300 µm in 120 s (CF_PyC_120). To evaluate the materials, various methods such as scanning electron microscopy (SEM), scanning transmission electron microscope (STEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and tensiometer techniques were used to study their microstructural, structural, chemical composition, surface morphology, and surface wettability. Assessing their applicability for contact with nervous tissue cells, the evaluation of cytotoxicity and biocompatibility using the SH-SY5Y human neuroblastoma cell line was performed. Viability and cytotoxicity tests (WST-1 and LDH release) along with cell morphology examination demonstrated that the CF_PyC_120 composites showed high biocompatibility compared to the reference sample (Pt wire), and the best adhesion of cells to the surface among all tested materials.

ZnO-decorated green-synthesized multi-doped carbon dots from Chlorella pyrenoidosa for sustainable photocatalytic carbamazepine degradation.

The promising green synthesis of carbon dots (CDs) from microalga Chlorella pyrenoidosa was achieved using simple hydrothermal and microwave-assisted methods. Doping of nanomaterials by nonmetals (N, S, and P) was confirmed by X-ray photoelectron spectroscopy (XPS), while the existence of metals in the CDs was confirmed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and transmission electron microscopy (TEM), and Mg, Ca, K, and Na were found as the dominant doped metals. The novel nanomaterials with excellent photoluminescence (PL) properties were used for the modification of ZnO obtained by a simple hydrothermal process. In this regard, a series of ZnO decorated with multi-doped carbon dots (xCDs) was prepared and their photocatalytic properties were evaluated. The ZnO-xCD photocatalysts were characterized by various advanced techniques including X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), XPS, Brunauer-Emmett-Teller (BET), PL, ultraviolet-visible (UV-vis) spectroscopy and electrochemical impedance spectroscopy (EIS) analysis. The photocatalytic behaviour of the obtained materials was investigated in the degradation of carbamazepine (CBZ). The influence of the synthesis method of xCDs and their content on the activity of the photocatalyst was examined. The photocatalyst ZnO modified with 3% xCDs obtained by the microwave-assisted method revealed the highest effectiveness for CBZ degradation and allowed for a first-order degradation rate of 2.85 times in comparison with non-modified ZnO. The improvement of the photocatalytic process was achieved by support with peroxymonosulphate resulting in up to 3.18 times a first order kinetic rate constant compared with that of simple photocatalysis in the presence of ZnO-xCDs. Taken together, our synthesized multi-doped CDs and their nanohybrids with ZnO, can be considered as promising candidates for photocatalytic applications.

Tailoring the Stability of Ti-Doped Sr2Fe1.4TixMo0.6-xO6-δ Electrode Materials for Solid Oxide Fuel Cells.

In this work, the stability of Sr2(FeMo)O6-δ-type perovskites was tailored by the substitution of Mo with Ti. Redox stable Sr2Fe1.4TixMo0.6-xO6-δ (x = 0.1, 0.2 and 0.3) perovskites were successfully obtained and evaluated as potential electrode materials for SOFCs. The crystal structure as a function of temperature, microstructure, redox stability, and thermal expansion properties in reducing and oxidizing atmospheres, oxygen content change, and transport properties in air and reducing conditions, as well as chemical stability and compatibility towards typical electrolytes have been systematically studied. All Sr2Fe1.4TixMo0.6-xO6-δ compounds exhibit a regular crystal structure with Pm-3m space group, showing excellent stability in oxidizing and reducing conditions. The increase of Ti-doping content in materials increases the thermal expansion coefficient (TEC), oxygen content change, and electrical conductivity in air, while it decreases the conductivity in reducing condition. All three materials are stable and compatible with studied electrolytes. Interestingly, redox stable Sr2Fe1.4Ti0.1Mo0.5O6-δ, possessing 1 µm grain size, low TEC (15.3 × 10-6 K-1), large oxygen content change of 0.72 mol·mol-1 between 30 and 900 °C, satisfactory conductivity of 4.1-7.3 S·cm-1 in 5% H2 at 600-800 °C, and good transport coefficients D and k, could be considered as a potential anode material for SOFCs, and are thus of great interest for further studies.

Influence of Heat Treatment of Electrospun Carbon Nanofibers on Biological Response.

The main aim of this study is to investigate the effect of fragmentation of electrospun carbon nanofibers (eCNFs) obtained at different temperatures, i.e., at 750 °C, 1000 °C, 1500 °C, 1750 °C and 2000 °C on the cellular response in vitro. In order to assess the influence of nanofibers on biological response, it was necessary to conduct physicochemical, microstructural and structural studies such as SEM, XPS, Raman spectroscopy, HRTEM and surface wettability of the obtained materials. During the in vitro study, all samples made contact with the human chondrocyte CHON-001 cell lines. The key study was to assess the genotoxicity of eCNFs using the comet test after 1 h or 24 h. Special attention was paid to the degree of crystallinity of the nanofibers, the dimensions of the degradation products and the presence of functional groups on their surface. A detailed analysis showed that the key determinant of the genotoxic effect is the surface chemistry. The presence of nitrogen-containing groups as a product of the decomposition of nitrile groups has an influence on the biological response, leading to mutations in the DNA. This effect was observed only for samples carbonized at lower temperatures, i.e., 750 °C and 1000 °C. These results are important with respect to selecting the temperature of thermal treatment of eCNFs dedicated for medical and environmental functions due to the minimization of the genotoxic effect of these materials.

Fe-Co-B Soft Magnetic Ribbons: Crystallization Process, Microstructure and Coercivity.

In this work, a detailed microstructural investigation of as-melt-spun and heat-treated Fe67Co20B13 ribbons was performed. The as-melt-spun ribbon was predominantly amorphous at room temperature. Subsequent heating demonstrated an amorphous to crystalline α-(Fe,Co) phase transition at 403 °C. In situ transmission electron microscopy observations, carried out at the temperature range of 25-500 °C and with the heating rate of 200 °C/min, showed that the first crystallized nuclei appeared at a temperature close to 370 °C. With a further increase of temperature, the volume of α-(Fe,Co) crystallites considerably increased. Moreover, the results showed that a heating rate of 200 °C/min provides for a fine and homogenous microstructure with the α-(Fe,Co) crystallites size three times smaller than when the ribbon is heated at 20 °C/min. The next step of this research concerned the influence of both the annealing time and temperature on the microstructure and coercivity of the ribbons. It was shown that annealing at 485 °C for a shorter time (2 s) led to materials with homogenous distribution of α-(Fe,Co) crystallites with a mean size of 30 nm dispersed in the residual amorphous matrix. This was reflected in the coercivity (20.5 A/m), which significantly depended on the volume fraction of crystallites, their size, and distribution.

Microstructure of Coatings on Nickel and Steel Platelets Obtained by Co-Milling with NiAl and CrB2 Powders.

Metal matrix composite coatings are developed to protect parts made from materials susceptible to wear, like nickel alloys or stainless steel. The industry-established deposition method is presently an atmospheric plasma spraying method since it allows the production of both well-adhering and thick coatings. Alternatively, similar coatings could be produced by co-milling of ceramic and alloyed powders together with metallic plates serving as substrates. It results in mechanical embedding of the powder particles into exposed metallic surfaces required coatings. The present experiment was aimed at the analysis of microstructure of such coatings obtained using NiAl and CrB2 powders. They were loaded together with nickel and stainless steel platelets into ball mill vials and rotated at 350 rpm for up to 32 h. This helped to produce coatings of a thickness up to ~40 µm. The optical, scanning, and transmission electron microscopy observations of the coatings led to conclusion that the higher the rotation speed of vials, the wider the intermixing zone between the coating and the substrate. Simultaneously, it was established that the total thickness of the coating deposited at specified conditions is limited by the brittleness of its nanocrystalline matrix. An increase in the hardness of the substrate results in a decrease of the intermixing zone. The above results indicate that even as the method based on mechanical embedding could so far produce thinner coatings than the plasma spraying, in the former case they are characterized by a more uniform nanocrystalline matrix with homogenously distributed fine ceramic particles.

Assessment of airway caliber in quantitative videobronchoscopy.

BACKGROUND: Quantitative assessment of airway caliber is generally confined to indirect methods. Fiberoptic bronchoscopy provides a direct view of the airways, but measurement of the internal size of bronchi in a standard examination is not possible. Using a special image analysis program, we developed a method allowing quantitative assessment of airway caliber by means of videobronchoscopic (VB) examination. OBJECTIVES: The purpose of the study was toshow that quantitative videobronchoscopy (VB coupled with a computer image analysis) allows direct and accurate measurement of the bronchi diameter. METHODS: To test our hypothesis, we measured the same areas of a bronchial tree in CT and in VB in 40 patients with diagnostic indications for both the procedures. RESULTS: We measured the diameters of 149 bronchi. The mean value of the difference between VB and CT measurements was equal to -0.071 mm and was not significantly different from 0 (p = 0.086). There was no obvious relation between the difference and the mean (r = 0.026, p = 0.745). The Bland Altman limits of agreement were L = -1.071 mm and U = 0.929 mm. We also assessed the bronchial diameter after endobronchial challenge and in patients with tracheobronchomalacia to show the application of this method for dynamic measurements. CONCLUSIONS: Quantitative videobronchoscopy allows the accurate and direct measurement of an airway caliber. It may be useful in clinical setting to quantify changes in a bronchial caliber (endobronchial masses, tracheobronchomalacia). Dynamic visualization of changes in airways may be useful in research, especially to explore the mechanics of airway narrowing.